Asked by Paula Durley on Jun 06, 2024
Verified
The following [3+2] cycloaddition was reported in Organic Letters, 2011, 402. Predict whether the reaction would be thermally or photochemically promoted. Justify your answer by showing overlap of the correct molecular orbitals. Assume the alkene is the electrophile.
Cycloaddition
A type of chemical reaction where two or more unsaturated molecules combine to form a cyclic adduct, important in the synthesis of heterocyclic compounds.
Organic Letters
A peer-reviewed scientific journal publishing original research articles in organic chemistry.
Molecular Orbitals
Orbitals that belong to a molecule as a whole, where electrons are considered to be delocalized over the entire molecule.
- Examine and forecast the results of cycloaddition reactions, including those induced by heat and light.
- Utilize molecular orbital diagrams to justify reaction mechanisms and predict products.
Verified Answer
Learning Objectives
- Examine and forecast the results of cycloaddition reactions, including those induced by heat and light.
- Utilize molecular orbital diagrams to justify reaction mechanisms and predict products.
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