Asked by Ramsha Saleem on Sep 22, 2024

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Verified

Among the butane conformers, which occur at energy minima on a graph of potential energy versus dihedral angle?

A) gauche only
B) eclipsed and totally eclipsed
C) gauche and anti
D) eclipsed only
E) anti only

Butane Conformers

Different spatial arrangements of atoms in butane that result from rotation around single bonds, affecting the molecule's energy.

Energy Minima

Points in a potential energy surface that represent stable states of a system, where any small displacement of particles leads to an increase in potential energy.

Dihedral Angle

The angle between two planes defined by four atoms, often used to describe the orientation of parts of a molecule relative to each other.

  • Determine the stability and energy differences between various conformations of alkanes.
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Verified Answer

DS
Daniel Soares5 days ago
Final Answer :
C
Explanation :
The anti conformer is the most stable of all the butane conformers and occurs at the energy minimum with a dihedral angle of 180 degrees. The gauche conformer occurs at a secondary energy minimum with a dihedral angle of 60 degrees or 300 degrees, while the eclipsed and totally eclipsed conformers occur at higher energy levels and are unstable. Therefore, the correct answer is C, as both the anti and gauche conformers occur at energy minima on the graph of potential energy versus dihedral angle.