Asked by ?? Th? Thanh Th?o on Sep 22, 2024

Given the following heats of combustion per CH2 group within the structure, which cyclic alkane has essentially no angle strain? (Ref: long-chain Alkane = 659 kJ/mol)

A) cyclobutane = 686 kJ/mol
B) cyclopentane = 664 kJ/mol
C) cyclohexane = 659 kJ/mol
D) cycloheptane = 662 kJ/mol
E) cyclooctane = 663 kJ/mol

Angle Strain

A form of strain in a cyclic molecule when bond angles deviate from their ideal values, leading to extra energy stored in the compound.

Heats of Combustion

The amount of heat released when a compound undergoes complete combustion with oxygen under standard conditions.

Cyclic Alkane

A saturated hydrocarbon in which the carbon atoms are arranged in a ring, with the formula CnH2n.

  • Determine the most stable conformations of cycloalkanes and recognize the absence or presence of angle strain.
  • Explain the relationship between molecular structure and heat of combustion in cycloalkanes.