Asked by LEANDRO MARTINEZ on Sep 26, 2024

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When L-(+) -lyxose is treated with nitric acid, which of the following results?

A) a racemic mixture of aldaric acids
B) an optically active aldaric acid
C) an optically inactive aldaric acid
D) an optically active aldonic acid
E) an optically inactive aldonic acid

Aldaric Acid

A type of sugar acid derived from aldoses by oxidation of both the aldehyde group and the primary alcohol group to carboxylic acids.

Optically Active

Describes a substance that can rotate the plane of polarized light, indicating chiral molecules.

Nitric Acid

A highly corrosive and toxic strong acid, used in the production of fertilizers, explosives, and in many organic syntheses.

  • Comprehend the principle of oxidation reactions and their resultant effects in carbohydrates.
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Verified Answer

AA
Abena Amaning1 day ago
Final Answer :
B
Explanation :
When L-(+)-lyxose is treated with nitric acid, it undergoes oxidation to form an aldaric acid. Since the starting material is optically active, the product remains optically active as well, thus forming an optically active aldaric acid. Nitric acid oxidation of sugars typically targets the aldehyde group (to form a carboxylic acid at one end) and the primary alcohol group (to form another carboxylic acid at the other end), resulting in an aldaric acid. The stereochemistry of the original sugar influences the optical activity of the product.