Asked by Emily Sharp on Sep 27, 2024
Which of the following terms best describes a Diels-Alder reaction?
A) a [4+2] cycloaddition
B) a [2+2] cycloaddition
C) a sigmatropic rearrangement
D) a 1,3-dipolar cycloaddition
E) a substitution reaction
Cycloaddition
A chemical reaction in which two or more unsaturated molecules (or parts of the same molecule) combine to form a cyclic compound.
Sigmatropic Rearrangement
A type of pericyclic reaction in which a σ-bond (sigma bond) changes position relative to a π system (pi system) within a molecule, following specific suprafacial or antarafacial pathways.
Diels-Alder
A chemical reaction between a diene and a dienophile, resulting in the formation of a cyclohexene derivative.
- Understand the principles of the Diels-Alder reaction, including its regiochemistry and the endo rule.
Learning Objectives
- Understand the principles of the Diels-Alder reaction, including its regiochemistry and the endo rule.